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INVENTION
Patent of the Russian Federation RU2164237
ADHESIVE FOR CONSTRUCTION WORKS
Applicant's name: Closed Joint-Stock Company "PLASTOUN"
The name of the inventor: Bull A.D.
The name of the patent holder: Closed Joint-Stock Company "PLASTOUN"
Address for correspondence: 140070, Moscow region, Luberetskiy reg., Tomilino village, Garshina street, 26A, Gratsiansky VI
Date of commencement of the patent: 1999.09.14
The invention relates to the field of building materials and can be used for gluing various building elements and parts, as well as for gluing tiles, linoleum and other materials. Adhesive for construction works contains: synthetic latex 5-30% , surfactant - product of mono- and dialkylphenol treatment with ethylene oxide or OP-10, OP-7 0.1-1.5 % , thickener 0.05-1 , 5% , alkali 0,05 - 5% , dispersant 0,1 - 1,5% , coalescent 0,05 - 3% , antifreeze 0,5 - 5,0 , biocide additive 0,01 - 1,0% , defoamer 0 , 01 - 1,0% , plasticizer 0,05 - 5,0% , antimony trioxide 3 - 5 , chalk 30 - 70% , quartz sand 0 - 25% , water the rest, the adhesive can contain talc and / or quartz Flour. The adhesive provides high strength properties and bonding quality.
DESCRIPTION OF THE INVENTION
The invention relates to the field of building materials and can be used for gluing various building elements and parts, as well as for gluing tiles, linoleum and other materials.
Known is an adhesive composition comprising a latex of a copolymer of butadiene with acrylonitrile and methacrylic acid, saponified with alkali ( see Russian patent 2,036,945, published June 9, 1995 ).
The closest analogue to the invention is an adhesive , H: isoprene-nitrile latex (dry weight) 90-100, filler 3-60, surfactant 0.3-3, thickener 0.1-2.5, thixotropic additive 0.1-2.5, 20 % Aqueous solution of ammonia or potash 0,1-2,5, water - the rest (see copyright certificate of the USSR No. 729227, published on April 27, 80).
The object of the invention is to increase the adhesion of the adhesive to the surface of the materials to be bonded.
The above object is achieved in that the adhesive for construction works, including synthetic latex, surfactant, thickener, alkali, filler and water, contains as a surfactant the product of treatment of mono- and dialkylphenols with ethylene oxide OP-7 or OP-10 , And as filler - chalk and quartz sand and additionally dispersant, coalescent, biocidal additive, antifreeze, antifoaming agent, plasticizer and antimony trioxide at the following proportions of components, mass%:
- Synthetic latex - 5-30
- The surfactant OP-7 or OP-10 is 0.1-1.5
- Thickener - 0.05-1.5
- Dispersant 0.1-1.5
- Coalescent 0.05-3
- Biocide additive - 0,01-1
- Antifreeze - 0,5-5
- Defoamer - 0,01-1
- The plasticizer is 0.05-5
- Antimony trioxide - 3-5
- Alkali - 0.05-5
- Sand - 0-25
- Chalk - 30-70
- Water - Other
In this case, the glue may additionally contain talc and / or quartz flour.
The adhesive is prepared as follows. First, prepare a 1-3% aqueous thickener solution and a 8-12% aqueous solution of the dispersant. Then the components for glue preparation are fed into the mixer.
The following components are used to prepare the glue:
- Latexes: DL-424, 430, XZ 92099, styrene-acrylic, under the contract with the firm "Dow Chem"; Primal 219N, styrene-acrylic, under the contract with the firm "Room and Haas"; Lacryl 21, styrene acrylic, MBM-5C, acrylic, manufacturer 000 "Orgkhimprom", Dzerzhinsk, respectively according to TU 2241-002-39251899-96 and TU 6-01-274-79; Movilit DM 771, 6610, DL 611, styreneacrylic dispersions, under contract with the firm "Hoechst".
- Acropolis 290 D-styrene acrylic dispersion, under contract with the firm BASF.
- Alkali: sodium hydroxide, TU 6-01-1306-85, ammonia water technical, GOST 3760-79.
- OP-7 is the product of processing a mixture of mono- and dialkylphenols with ethylene oxide, GOST 8433-81.
- Sodium tripolyphosphate, GOST 13493-86.
- Methocel - hydroxypropyl methylcellulose, under contract with the firm "Dow Chem".
- Sulfacel - cellulose thickener, TU 6-55-221-1473-97
- Natrosol 250 HBR - cellulose thickener of the company "Aqvalon".
- Akrisol TT-935 is an anionic rheology modifier based on acrylic latex, under contract with the firm "Room and Haas".
- Sodium carboxymethylcellulose, OST 6-05-386-80.
- Orotan 731K, dispersant on contract with the firm "Room and Haas".
- Dispex - sodium salt of polycarboxylic acid, under the contract with the firm Allied Colloids.
- Calgon - dispersant additive, under the contract with the firm "VK hadenvilz"
- Defoamer 139-282 is a product based on organosilicon compounds, TU 6-02-1-529-86.
- Agitan 230 is a mixture of modified non-ionic fatty compounds, a hydrophobic organosilicon compound and hydrocarbons, under contract with the firm Room and Haas.
- Lumitan 3065 - defoamer firm "BASF".
- Nopko NXZ, Foamex 1488, Foamaster NXZ - antifoaming agent of the company "Henkel-Nopco".
- BIK 033 is a defoamer from Byk Chemic.
- Diethylene- or ethylene glycol-antifreeze, respectively, according to GOST 10136-77 and GOST 197-10-83.
- Ethylcellosolve, GOST 8313-88.
- White spirit, coalescent, GOST 3134-78.
- Butyldiglycol acetate, coalescent, under contract with the firm "Union Carbide etc."
- Texanol is a diol ether, a solvent, a kaorescent of Eastman Chemical.
- Luzolvan is a diisobutyl ether of a mixture of dicarboxylic acids produced by BASF.
- Dovanol - methyl, propyl or n-butyl esters of propylene glycols, under contract with the firm "Dow Chem".
- Metatin is a fungicide based on acyclic and heterocyclic nitrogen compounds contracted by ACIMA.
- Cato - LXE-biocide of a wide spectrum of action, a product of firm "РООМ and ХААС".
- Dibutyl phthalate - plasticizer, GOST 8728-88.
- Dioctyl phthalate - plasticizer, GOST 8728-88.
- EDOS - a mixture of the forms and oligomers of dioxane alcohols, TU 2493-003-13004749-93.
- DAP-di-n-alkyl phthalate, "Salavatorgsintez".
- Plasticine 3080, 3060 - alkylphenyl ether of propylene glycol, plasticizer of the company "BASF".
- Mel - calcium carbonate, with the main fraction 5,15,40,130 microns, GOST 12085-88.
- Sand quartz Volgograd, Ramensky or Chelyabinsk fractions 0,1-0,3 mm.
- Talc - filler, magnesium hydrosilicate, product of the company "Finnminerals".
- Antimony trioxide, TU 48-14-1-82.
Examples of specific performance of the adhesive and its properties are given in Table 1 and 2, respectively.
As follows from the data given, the adhesive according to the invention provides a high quality of gluing.
CLAIM
-
Adhesive for construction works, including synthetic latex, surfactant, thickener, alkali, filler and water, characterized in that, as a surfactant, it contains the product of treatment of mono- and dialkylphenols with ethylene oxide OP-7 or OP-10, And as a filler, chalk and quartz sand and additionally dispersant, coalescent, biocidal additive, antifreeze, antifoam, plasticizer and antimony trioxide with the following proportions of components, mass%:
Synthetic latex - 5-30
The surfactant OP-7 or OP-10 is 0.1-1.5
Thickener - 0.05-1.5
Dispersant 0.1-1.5
Coalescent - 0.05-3
Biocide additive - 0,01-1
Antifreeze - 0,5-5
Defoamer - 0,01-1
The plasticizer is 0.05-5
Antimony trioxide - 3-5
Alkali - 0.05-5
Sand - 0-25
Chalk - 30-70
Water - Other
The adhesive for construction works of claim 1, further comprising talc and / or quartz flour.
print version
Date of publication 11.11.2006гг
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